RESEARCH ON A NEW CLASS OF INORGANIC MOLECULES CONSISTING BASICALLY OF SULFUR AND NITROGEN

摘要

The silicon amines, (C6H5)3SiNH2, (C2H5)3SiNH2 and [(CH3)3Si]2NH have been found to react with either S2Cl2 or SCl2. No pure silicon derivatives of tetrasulfur tetranitride, S4N4, of the type (R3Si)4S4N4, (R3Si)3S5N2, (R3SiNs)x etc. analogous to those formed by carbon amines, could be isolated from the reaction products.nNH2CN, CO(NH2)2 and CO (NHCH3)2 were found to react with S2Cl2 to giver complex polymeric materials.