Compilation of Rate Constants for the Reactions of Metal Ions in Unusual Valency States,

摘要

Kinetic data have been compiled for reactions of uncommon oxidation states of metals which are produced by radiolysis of aqueous solutions of metal ions. Most of the reaction rates are for transient species,and the rates were determined by pulse radiolysis;some data were obtained by flash photolysis and gamma radiolysis. Metal ions from Groups IB,IIB,IIIA,IVA,VIB,VIIB, VIIIB,and the lanthanides are included in the compilation. Copyright (c) 1978by the Secretary of Commerce.