Hydrolysis Rate Constants for Enhancing Property-Reactivity Relationships

摘要

The report examines the rate constants for hydrolysis in water of 10 classes of organic compounds with the objective of establishing new or expanding existing property-reactivity correlations. These relationships can then be used to predict the environmental hydrolysis fate of chemicals that have similar molecular structure. The compound classes covered by the report include: aliphatic and aromatic carboxylate esters, alkyl and aromatic halides, amides, carbamates, epoxides, nitriles, phosphate esters, alkylating agents, halogenated ethers, and oxidized sulfur compounds.