Grafting of 2 (2-Hydroxy-5-Vinylphenyl) 2H-Benzotriazole onto Polymers with Aliphatic Groups. Synthesis and Polymerization of 2 (2-Hydroxy-5-Isopropenylphenyl) 2H-Benzotriazole and a New Synthesis of 2 (2-Hydroxy-5-Vinylphenyl) 2H

摘要

Successful grafting of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole onto saturated aliphatic C-H groups of polymers has been accomplished. When the grafting reaction was carried out in chlorobenzene at 150 C = 160 C with di-tertiarybutylperoxide as the grafting initiator, grafts as high as 20 percent - 30 percent at a grafting efficiency of 50 percent and 80 percent have readily been obtained. The grafting reaction was carried out in tubes sealed under high vacuum since trace amounts of oxygen cause complete inhibition of the grafting reaction by the phenolic monomer. On a variety of different polymers including atactic polypropylene, ethylene/vinyl acetate copolymer, poly(methyl methacrylate), poly(butyl acrylate), and polycarbonate were used.