Carbon monoxide oxidation over three different states of copper: Development of a model metal oxide catalyst

摘要

Carbon monoxide oxidation was performed over the three different oxidation states of copper -- metallic (Cu), copper (I) oxide (Cu(sub 2)O), and copper (II) oxide (CuO) as a test case for developing a model metal oxide catalyst amenable to study by the methods of modern surface science and catalysis. Copper was deposited and oxidized on oxidized supports of aluminum, silicon, molybdenum, tantalum, stainless steel, and iron as well as on graphite. The catalytic activity was found to decrease with increasing oxidation state (Cu > Cu(sub 2)O > CuO) and the activation energy increased with increasing oxidation state (Cu, 9 kcal/mol < Cu(sub 2)O, 14 kcal/mol < CuO, 17 kcal/mol). Reaction mechanisms were determined for the different oxidation states. Lastly, NO reduction by CO was studied. A Cu and CuO catalyst were exposed to an equal mixture of CO and NO at 300--350 C to observe the production of N(sub 2) and CO(sub 2). At the end of each reaction, the catalyst was found to be Cu(sub 2)O. There is a need to study the kinetics of this reaction over the different oxidation states of copper.