Catalytic applications of mono- and dinuclear complexes containing metal-carbon sigma bonds. Final report, November 1, 1993--October 31, 1996

摘要

This report discusses results from several studies involved in the project. Investigations include: vibrational models for surface olefins and alkylidenes; mechanism of the formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; determination by nematic phase NMR of the structure of mononuclear and dinuclear ethylene complexes of osmium; and generation of ``coordinatively unsaturated`` complexes by protonation of methyl osmium complexes.