Investigation of the breakdown products produced from electrical discharge in selected CFC replacement fluids

摘要

LLNL personnel have designed and constructed a special purpose electrical test stand to evaluate CFCs and CFC replacement fluids under simulated AC, DC, and pulsed breakdown conditions. The test stand includes an electrical diagnostic system which allows the measurement of breakdown voltage, discharge current, arc power, and energy associated with each pulse. The appropriate data that is collected in order to correlate the quantity of by-products produced with the pertinent control variables, such as voltage, current, pulse width, pulse repetition frequency, and energy. Along with the electrical test stand, LLNL has extensive chemical analysis facilities that enable us to perform gas chromatographic and gas chromatographic-mass spectrometric analysis of various fluids to identify and quantify the breakdown products formed under various scenarios of electrical energy deposition.