Origin of the 871-keV gamma ray and the ``oxide'' attribute

摘要

This work concludes the investigation of the oxide attribute of current interest for the characterization of stored plutonium. Originally it was believed that the presence of oxide could be ascertained by measurement of the 871-keV line in a high-resolution gamma-ray spectrum. However, recent work has suggested that the 871-keV gamma ray in plutonium oxide arises from the reaction {sup 14}N({alpha},p){sup 17}O rather than the inelastic scattering reaction {sup 17}O({alpha},{alpha}{prime}){sup 17}O*. This conclusion, though initially surprising, was obtained during efforts to determine the relative importance of americium and plutonium alpha-particle decay for the production of the 871-keV gamma ray. Several questions were raised by previous experiments: What role, if any does {sup 17}O have in the generation of the 871-keV gamma ray? How does sufficient nitrogen come to be present in plutonium oxide? Under what conditions is the 871-keV gamma ray measurable in plutonium oxide? This paper describes the answers to these questions.