New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells. (Quarterly Report for March 31, 2006 to June 30, 2006).

摘要

Operation of SOFCs at intermediate temperatures (500 800 degrees C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode - electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm(sup 2) at 0.7 V in combination with YSZ at 700 degrees C and with GDC, LSGM or bismuth oxide based electrolytes at 600 degrees C. The performance targets imply an area specific resistance of approximately 0.5 Ocm(sup 2) for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, further measurements of the oxygen deficient double perovskite PrBaCo(sub 2)O(sub 5.5+8) are reported. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. Preliminary measurements in symmetric cells have shown low ASR values at 600 degrees C. Here we describe the first complete cell measurements on Ni/CGO/CGO/PBCO/CGO cells.