Anodic Behavior of Alloy 22 in High Nitrate Brines at Temperatures Higher than 100 degree C

摘要

Alloy 22 (N06022) may be susceptible to crevice corrosion in chloride solutions. Nitrate acts as an inhibitor to crevice corrosion. Several papers have been published regarding the effect of nitrate on the corrosion resistance of Alloy 22 at temperatures 100 degrees C and lower. However, very little is known about the behavior of this alloy in highly concentrated brines at temperatures above 100 degrees C. In the current work, electrochemical tests have been carried out to explore the anodic behavior of Alloy 22 in high chloride high nitrate electrolytes at temperatures as high as 160 degrees C at ambient atmospheres. Even though Alloy 22 may adopt corrosion potentials in the order of +0.5 V (in the saturated silver chloride scale), it does not suffer crevice corrosion if there is high nitrate in the solution. That is, the inhibitive effect of nitrate on crevice corrosion is active for temperatures higher than 100 degrees C.