Preliminary Results from a Quasi-Classical Trajectory Analysis of the H + O sub 2 Implies OH + O Reaction

摘要

This report compares the results of a quasi-classical analysis with experimental results for the rate coefficient of the H + O sub 2 implies OH + O reaction in the high temperature (1250 to 2500 K) regime. The trajectory results are in good agreement with Schott's experiments but are not consistent with the Leeds recommendation in this temperature range. It is deduced that vibrational nonequilibrium effects are not likely to be responsible for the non-Arrhenius temperature dependence of this reaction. (ERA citation 04:024139)