Novel Concepts for the Compression of Large Volumes of Carbon Dioxide

摘要

In the effort to reduce the release of CO{sub 2} greenhouse gases to the atmosphere, sequestration of CO{sub 2} from Integrated Gasification Combined Cycle (IGCC) and Oxy-Fuel power plants is being pursued. This approach, however, requires significant compression power to boost the pressure to typical pipeline levels. The penalty can be as high as 8% to 12% on a typical IGCC plant. The goal of this research is to reduce this penalty through novel compression concepts and integration with existing IGCC processes. The primary objective of the study of novel CO{sub 2} compression concepts is to boost the pressure of CO{sub 2} to pipeline pressures with the minimal amount of energy required. Fundamental thermodynamics were studied to explore pressure rise in both liquid and gaseous states. For gaseous compression, the project investigated novel methods to compress CO{sub 2} while removing the heat of compression internal to the compressor. The high-pressure ratio due to the delivery pressure of the CO{sub 2} for enhanced oil recovery results in significant heat of compression. Since less energy is required to boost the pressure of a cooler gas stream, both upstream and interstage cooling is desirable. While isothermal compression has been utilized in some services, it has not been optimized for the IGCC environment. This project determined the optimum compressor configuration and developed technology concepts for internal heat removal. Other compression options using liquefied CO{sub 2} and cryogenic pumping were explored as well. Preliminary analysis indicates up to a 35% reduction in power is possible with the new concepts being considered.