Advanced Research in Coal Gasification Process Modification Technology: Catalytic Cracking of Aromatic Hydrocarbons. Topical Report, 1 October 1984-31 June 1985

摘要

The objective of this work is to screen inexpensive materials for potential use as disposable aromatic hydrocarbon (AHC) cracking catalysts in the reaction zone of the coal gasifier or in a fixed bed downstream from the gasifier. The approach is based on the conclusions reported in the literature that iron in a reduced state is an effective catalyst for AHC destruction. It therefore follows that chars or minerals with high iron content, high porosity, and high internal surface area will provide the most effective catalysts. We have screened all six of the following iron containing minerals: Siderite, Ankerite, Hematite, Magnetite, Pyrite, and Jarosite. The experimental tests measure the catalytic activity of these minerals for cracking benzene over the parameter range relevant to coal gasifier operation. Simulated coal gas containing 200 to 2000 ppM of model aromatic molecules will be used in all experiments and destruction of benzene will be measured over the temperature range 400 to 1000 exp 0 C. The porosity and surface area of these minerals (partially decomposed in coal gas) will be determined and utilized in a computer model describing pore structure, species transport and surface chemistry to interpret the reactivity data in terms of the intrinsic reactivity of the reduced state of each mineral. These results will provide a basis for catalyst selection, coal selection and economic comparison. 3 refs., 15 figs., 3 tabs. (ERA citation 11:006893)