Numerical Simulation of Alteration of Sodium Bentonite by Diffusion of Ionic Groundwater Components

摘要

Experiments measuring the movement of trace amounts of radionuclides through compacted bentonite have typically used unaltered bentonite. Models based on experiments such as these may not lead to accurate predictions of the migration through altered or partially altered bentonite of radionuclides that undergo ion exchange. To address this problem, we have modified an existing transport code to include ion exchange and aqueous complexation reactions. The code is thus able to simulate the diffusion of major ionic groundwater components through bentonite and reactions between the bentonite and groundwater. Numerical simulations have been made to investigate the conversion of sodium bentonite to calcium bentonite for a reference groundwater characteristic of deep granitic formations. 20 refs., 2 figs., 2 tabs. (ERA citation 13:021077)