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Voltage delay in Li/SOCl(sub 2) cells for artillery applications at (minus)35(degrees)C.

机译:用于炮兵应用的Li / sOCl(sub 2)电池中的电压延迟在(负)35(度)C。

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Sandia National Laboratories is developing active Li/SOCl(sub 2) cells for use in Artillery-Fired Atomic Projectiles. Voltage delay is the primary mode of electrochemical failure in these cells at (minus)35(degree)C. To minimize this anode polarization, the anode passivation is inhibited by adding chloromethyl chlorosulfate (CMCS) to the sulfur dioxide complex of lithium tetrachloroaluminate (LiAlCl(sub 4)(center dot)SO(sub 2)) in the cell electrolyte. 3 refs., 5 figs.

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