Development of precipitated iron catalysts with improved stability. Technical progress report No. 5, September 16, 1988--December 16, 1988

摘要

The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H(sub 2) conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal liters per hr per gram iron (NL/hr/gFe) using a synthesis gas with 0.5-1.0 H(sub 2):CO ratio in a slurry reactor.