首页> 美国政府科技报告 >Picosecond infrared study of intramolecular energy transfer in ((phen)(CO)(sub 3)Re(sup I)(NC)Ru(sup II)(CN)(bpy)(sub 2))(sup +).

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Picosecond infrared study of intramolecular energy transfer in ((phen)(CO)(sub 3)Re(sup I)(NC)Ru(sup II)(CN)(bpy)(sub 2))(sup +).

机译：在（（phen）（CO）（sub 3）Re（sup I）（NC）Ru（sup II）（CN）（bpy）（sub 2））（sup +）中的分子内能量转移的皮秒红外研究。

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The dynamics and mechanism of intramolecular energy transfer in ((phen)(CO)(sub 3)Re(sup I)(NC)Ru(sup II)(CN)(bpy)(sub 2))+ following metal-to-ligand charge transfer excitation have been studied using picosecond infrared spectroscopy.

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作者
R. B. Dyer K. A. Peterson K. C. Gordon W. H. Woodruff J. R. Schoonover;
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年度 1992
页码 1-7
总页数 7
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Absorption Spectroscopy; Charge Exchange; EDB/400102; EDB/400201; EDB/400500; Energy Transfer; Excitation; Infrared Spectra; Meetings; Rhenium Complexes; Ruthenium Complexes;

机译：吸收光谱;电荷交换; EDB / 400102; EDB / 400201; EDB / 400500;能量转移;激发;红外光谱;会议;铼配合物;钌配合物;

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专利

1. Excited state electronic properties of the [(phen)(OC)_3Re~I(NC)Ru~(II)-(bpy)_2(CN)]PF_6 and [(phen)(OC)_3Re~I(CN)Ru(II)(bpy)_2(CN)]PF_6 limkage isomers [J] . Thompson David W., Schoonover Jon R. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第21期

机译：[（phen）（OC）_3Re〜I（NC）Ru〜（II）-（bpy）_2（CN）] PF_6和[（phen）（OC）_3Re〜I（CN）Ru（ II）（bpy）_2（CN）] PF_6 limkage异构体
2. Orbital Specific Charge Transfer Distances, Solvent Reorganization Energies, and Electronic Coupling Energies: Electronic Stark Effect Studies of Parallel and Orthogonal Intervalence Transfer in (NC)_5Os~ Ⅱ-CN-Ru~Ⅲ(NH_3)_5~- [J] . Laba Karki, Joseph T. Hupp Journal of the American Chemical Society . 1997,第17期

机译：轨道比电荷转移距离，溶剂重组能和电子耦合能：（NC）_5Os〜Ⅱ-CN-Ru〜Ⅲ（NH_3）_5〜-中平行和正交间隔转移的电子斯塔克效应研究
3. Study on Estimating the Contribution to the Transfer Free Energies of Complex Ions. Part II. [Fe(CN)_(2n)(bpy)_((3-n))]~((2-2n)+) from Water to a Water-Ethanol Mixed Solvent [J] . Takao Tarui Bulletin of the Chemical Society of Japan . 2002,第3期

机译：估计对复杂离子的自由转移能量的贡献的研究。第二部分[Fe（CN）_（2n）（bpy）_（（3-n））]〜（（2-2n）+）从水到水-乙醇混合溶剂
4. PHOTOINDUCED INTRAMOLECULAR ELECTRON TRANSFER IN A Mn_2~(II,II)-RU~(II)-(NDI)_2 MOLECULAR TRIAD LEADING TO A LONG-LIVED CHARGE SEPARATED STATE - MIMICKING THE ELECTRON TRANSFER CHAIN IN PHOTOSYSTEM-II [C] . Nizamuddin Shaikh, Olof Johansson, Magnus Borgstrom, International Congress of Photosynthesis . 2005

机译：Mn_2〜（II，II）中的光突出的分子内电子转移 - （II） - （NDI） - （NDI）_2分子三合会导致长寿命电荷分离状态 - 模仿照相系统-II中的电子转移链
5. Photoinduced intramolecular energy transfer in rigidly bridged bimetallic Ru(II) complexes [D] . Kim, Won Yong 1997

机译：刚性桥联双金属Ru（II）配合物的光诱导分子内能量转移
6. pH-Driven Mechanistic Switching from Electron Transfer to Energy Transfer between Ru(bpy)32+ and Ferrocene Derivatives [O] . Claire Drolen, Eric Conklin, Stephen J. Hetterich, -1

机译：pH驱动的Ru（bpy）3 2+与二茂铁衍生物之间从电子转移到能量转移的机理转换
7. Ultrafast Photochemical Dissociation of an Equatorial CO Ligand from trans(X, X)-Ru(X)2(CO)2(bpy) (X = Cl, Br, I): A Picosecond Time-Resolved Infrared Spectroscopic and DFT Computational Study [O] . -1

机译：Urtrafast PhotoPermication解离来自反 - 逆（x，x）-ru（x）2（co）2（bpy）（x = cl，br，i）的赤道Co配体的解离：Pic秒是分辨的红外光谱和DFT计算研究
8. Interligand and Charge-Transfer Emission from (Ru(bpy) (HDPA)2) (2+): A Dual Emitting Ru(II) Complex [R] . Blakley, R. L., Myrick, M. L., DeArmond, M. K. 1986

机译：来自（Ru（bpy）（HDpa）2）（2+）的配位和电荷转移发射：双发射Ru（II）配合物

Picosecond infrared study of intramolecular energy transfer in ((phen)(CO)(sub 3)Re(sup I)(NC)Ru(sup II)(CN)(bpy)(sub 2))(sup +).

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