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Factors Affecting Chelation of Carboxylates to cis-Diaqua Co(III) Complexes:Implications on the Reactivity of the Metal Complexes for Hydrolyzing Esters, Amides, Nitriles, and Phosphates

机译：影响羧酸盐与顺式 - 二型Co（III）配合物螯合作用的因素：金属配合物对水解酯，酰胺，腈和磷酸盐的反应性的影响

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The equilibrium constant for chelation of carboxylates to cis-diaqua tetraamineCo(III) complexes is highly sensitive to the tetraamine ligand structure, basicity of the chelating carboxylate and solvent polarity. Cis-Diaqua tetramine Co(III) complexes that easily accommodate chelation of carboxylates are also highly reactive for hydrolyzing carboxyl esters, amides, nitriles, and phosphate esters. jg.

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Connolly, J. A.; Kim, J. H.; Banaszczyk, M.; Drouin, M.; Chin, J.;
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年度 1995
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总页数 7
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Chelation; Reactivities; Amides; Esters; Hydrolysis; Nitriles; Cobalt; Phosphates; Metal complexes; Reprints; Equilibrium(General); Solvents; Polarity; Carboxyl radicals;

机译：螯合作用;反应活性;酰胺;酯类;水解;腈类;钴;磷酸盐;金属络合物;重印;平衡（一般）;溶剂;极性;羧基;
入库时间 2022-08-29 11:13:29

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1. FACTORS AFFECTING CHELATION OF CARBOXYLATES TO CIS-DIAQUA CO(III) COMPLEXES - IMPLICATIONS ON THE REACTIVITY OF THE METAL COMPLEXES FOR HYDROLYZING ESTERS, AMIDES, NITRILES, AND PHOSPHATES [J] . Connolly JA., Banaszczyk M., Drouin M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第5期

机译：影响羧酸盐与CIS-DIACO CO（III）配合物螯合的因素-对金属配合物水解酯，酰胺，腈和磷酸盐的反应性的影响
2. Chemistry and reactivity of dinuclear iron oxamate complexes: alkane oxidation with hydrogen peroxide catalysed by an oxo-bridged diiron(III) complex with amide and carboxylate ligation [J] . Pardo E, Lloret F, Carrasco R, Inorganica Chimica Acta . 2004,第9期

机译：双核草酸铁配合物的化学和反应活性：氧桥联二铁（III）配合物与酰胺和羧酸酯的连接催化过氧化氢的烷烃氧化
3. Carboxylic Groups as Cofactors in the Lanthanide-Catalyzed Hydrolysis of Phosphate Esters. Stabilities of Europium(III) Complexes with Aza-benzo-15-crown-5 Ether Derivatives and Their Catalytic Activity vs Bis(p-nitrophenyl)phosphate and DNA [J] . Anne Roigk, Olga V. Yescheulova, Yury V. Fedorov, Organic letters . 1999,第6期

机译：在镧系元素催化的磷酸酯水解中作为辅因子的羧酸基。 A与三氮杂苯并15冠5醚衍生物的配合物的稳定性及其对磷酸双（对硝基苯基）酯和DNA的催化活性
4. Protection of Labile Phosphate Ester Groups by Metal Complexes Reveal Dependence on Charge and Size of Interacting Metals [C] . Frank Kjeldsen, Simon Svane, Thomas j.d. Jorgensen, International Mass Spectrometry Conference . 2014

机译：通过金属配合物保护不稳定的磷酸酯基团透露对相互作用金属的电荷和尺寸的依赖性
5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。
6. Catalytic Ester–Amide Exchange Using Group (IV) Metal Alkoxide–Activator Complexes [O] . Chong Han, Jonathan P. Lee, Emil Lobkovsky, -1

机译：使用第四族金属醇盐-活化剂配合物催化酯-酰胺交换
7. The Stereochemistry and Reactivity of Metal-Schiff Base Complexes. IV. The Stereoselectivity ofN,N′-Ethylenebis(α-methylsalicylideneaminato)cobalt(III) Complexes withN-Benzyl-L-alanine,N-Methyl-L-alanine, andN-Benzyl-N-Methyl-L-alanine, and the Stereospecificity of 1S, 2S)-N,N′-1,2-Cyclohexylenebis(salicylideneaminato)cobalt(III) Complexes towardN-Benzyl-L-alanine [O] . Yuki Fujii, Makoto Matsufuru, Akira Saito, 1981

机译：金属席夫碱基复合物的立体化学与反应性。 IV。 Nn，N'-乙基甲基硅氧烷氨基氨基氨基氨基甲酰基钴（III）配合物的立体选择性，N-苄基-L-丙氨酸，N-甲基-L-丙氨酸，AndN-苄基-N-甲基-1-丙氨酸及其立体特异性1S，2S）-N，N'-1,2-环己烯比（水杨酰基氨基甲酸酯）钴（III）复合物，甲苄基-L-丙氨酸
8. Synthetic Catalysts that Hydrolyze Phosphate and Carboxylate Esters. [R] . Czarnik, A. W. 1992

机译：合成催化剂水解磷酸酯和羧酸酯。

Factors Affecting Chelation of Carboxylates to cis-Diaqua Co(III) Complexes:Implications on the Reactivity of the Metal Complexes for Hydrolyzing Esters, Amides, Nitriles, and Phosphates

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