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Functionalization of Reactive Polymers by Metalation with Superbases followed byReaction with Electrophiles

机译：反应性聚合物的功能化通过超高效金属化，然后与亲电子反应

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In order to test novel routes for the functionalization of polyolefins,hydrocarbon-soluble superbases have been used for the selective metalation of a

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Frechet, J. M.; Steinke, J. H.; Haque, S. A.; Wynne, K. J.;
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年度 1996
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总页数 32
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Polymers; Reactivities; Bases(Chemistry); Olefin polymers; Metalation; Test andevaluation; Metals; Cations; Methyl radicals; Molecules; Styrenes; Spectrometry; Cesium; Quenching; Lithium; Electrons; Hydrocarbons; Benzyl radicals; Polyethylene plastics; Al;

机译：聚合物;反应活性;碱（化学）;烯烃聚合物;金属化;测试和评价;金属;阳离子;甲基;分子;苯乙烯;光谱测定;铯;猝灭;锂;电子;碳氢化合物;苄基;聚乙烯塑料;铝;

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专利

1. CONTROLLED FUNCTIONALIZATION OF POLYSTYRENE - INTRODUCTION OF REACTIVE GROUPS BY MULTISITE METALATION WITH SUPERBASE AND REACTION WITH ELECTROPHILES [J] . Lochmann L., Frechet JMJ. Macromolecules . 1996,第5期

机译：聚苯乙烯的控制功能-超碱多元金属电镀与电解质反应引入活性基。
2. METALATION, A NOVEL ROUTE FOR THE FUNCTIONALIZATION OF REACTIVE ELASTOMERS .1. SUPERBASES IN THE METALATION OF POLY(ISOBUTYLENE-CO-P-METHYLSTYRENE) [J] . Steinke JHG., Frechet JMJ., Wang HC., Macromolecules . 1996,第19期

机译：金属化，活性弹性体功能化的新途径1。聚（异丁烯-CO-P-甲基苯乙烯）金属化中的超碱
3. Using electrophile-functionalized metallocene intermediates in the design of olefin polymerization catalysts [J] . Paul A. Deck, Owen W. Lofthus, Xu Cheng Polymer Preprints . 2000,第2期

机译：在烯烃聚合催化剂的设计中使用亲电子官能化的茂金属中间体
4. Surface functionalization of metallized polymer webs via vacuum deposited radiation cured polymer coatings [C] . A.Yiallizis, R.Ellwanger, A.Boufelfel International conference on vacuum web coating . 1995

机译：通过真空沉积的辐射固化聚合物涂层对金属化聚合物纤维网进行表面功能化
5. Small molecule functionalization and catalysis by first row transition metals supported by redox-active and electrophile-responsive pincer ligands. [D] . Cook, Brian J. 2016

机译：小分子功能化和催化的第一行过渡金属由氧化还原活性和亲电性钳夹配体支撑。
6. Synthesis of Ultrahigh Molecular Weight Polymers Containing Reactive Functionality with Low PDIs by Polymerizations of Long-Chain α-Olefins in the Presence of Their Nonconjugated Dienes by Cp*TiMe2(O-26-iPr2C6H3)–Borate Catalyst [O] . Kotohiro Nomura, Sarntamon Pengoubol, Wannida Apisuk 2020

机译：Cp * TiMe2（O-26-iPr2C6H3）-硼酸盐催化剂在长链α-烯烃非共轭二烯存在下的聚合反应合成具有低PDI活性的超高分子量聚合物
7. Reaction of metallated tert-butyl(phenyl)phosphane oxide with electrophiles as a route to functionalized tertiary phosphane oxides : Alkylation reactions [O] . Haynes RK, Au Yeung TL, Chan WK, 2000

机译：金属化叔丁基（苯基）膦氧化物与亲电试剂的反应，作为官能化叔膦氧化物的途径：烷基化反应

Functionalization of Reactive Polymers by Metalation with Superbases followed byReaction with Electrophiles

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