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Organophosphoranyl Radicals and Organophosphonate Derivatives -- Structure,Spectroscopy Reactivity

机译：有机磷酰基自由基和有机膦酸酯衍生物 - 结构，光谱反应性

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摘要

Final summary of contract work on elucidating the mechanism of P-C bond cleavagein the biodegradation of organophosphorus weapons agents.

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作者
Cramer, C. J.;
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年度 1997
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总页数 8
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Chemical warfare agents; Organic phosphorus compounds; Mathematical models; Computations; Spectroscopy; Reactivities; Chemical bonds; Toxic agents; Molecular structure; Biodegradation; Organic radicals; Cleavage; G agents;

机译：化学战剂;有机磷化合物;数学模型;计算;光谱学;反应性;化学键;毒性剂;分子结构;生物降解;有机基团;裂解; G剂;

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专利

1. Structure-reactivity relationships in reactions of alkane radical cations - Study of the proton transfer from alkane radical cations to alkane molecules in gamma-irradiated disordered CCl3F/alkane systems by ESR spectroscopy at cryogenic temperatures [J] . Ceulemans J. Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 1998,第14期

机译：烷烃自由基阳离子反应中的结构反应性关系-在低温下通过ESR光谱研究γ辐照的无序CCl3F /烷烃体系中烷烃自由基阳离子向烷烃分子的质子转移
2. PREPARATION AND SPECTROSCOPIES OF LAYERED ZIRCONIUM ORGANOPHOSPHONATES CONTAINING PYRIDINIUM AND ITS DERIVATIVE CATIONS [J] . Okuno S., Matsubayashi GE. Inorganica Chimica Acta . 1995,第1a2期

机译：含吡啶及其衍生物阳离子的层状锆有机磷的制备和光谱
3. Structure and Reactivity of Radicals Produced by Photocleavage of Oxime Ester Compounds Studied by Time-resolved Electron Paramagnetic Resonance Spectroscopy [J] . Yusuke Miyake, Hirona Takahashi, Nobuyuki Akai Chemistry Letters . 2014,第8期

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4. Structure of Radical Anions and Cations of Cysteine Derivatives Studied by Ion Spectroscopy: A Case Study of N-Acetyl Cysteine [C] . Sandra Osburn, Giel Berden, Jos Oomens, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2011

机译：离子光谱研究基团阴离子和半胱氨酸衍生物的结构的结构：一种N-乙酰半胱氨酸的案例研究
5. Study of the structure and reactivity of the radical cations and anions of cysteine, its derivatives, and cysteine-containing peptides using ion-molecule reactions, infrared multi-photon dissociation spectroscopy, and density functional theory calculations. [D] . Osburn, Sandra. 2013

机译：使用离子分子反应，红外多光子解离光谱和密度泛函理论计算研究半胱氨酸，其衍生物和含半胱氨酸的肽的自由基阳离子和阴离子的结构和反应性。
6. Structure-dependent reactivity of oxyfunctionalized acetophenones in the photooxidation of DNA: base oxidation and strand breaks through photolytic radical formation (spin trapping EPR spectroscopy transient kinetics) versus photosensitization (electron transfer hydrogen-atom abstraction) [O] . Waldemar Adam, Markus A. Arnold, Werner M. Nau, 2001

机译：氧官能化的苯乙酮在DNA的光氧化中的结构依赖性反应性：通过光解自由基的形成（自旋俘获EPR光谱瞬态动力学）与光敏化（电子转移氢原子抽象）形成碱基氧化和链断裂
7. Structure-dependent reactivity of oxyfunctionalized acetophenones in the photooxidation of DNA: base oxidation and strand breaks through photolytic radical formation (spin trapping, EPR spectroscopy, transient kinetics) versus photosensitization (electron transfer, hydrogen-atom abstraction) [O] . Adam, Waldemar, Arnold, Markus A., Nau, Werner M., 2017

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8. Reactivity of the Carbonate Radical with Aniline Derivatives [R] . Larson, R. A. , Zepp, R. G. 1988

机译：碳酸盐自由基与苯胺衍生物的反应性

Organophosphoranyl Radicals and Organophosphonate Derivatives -- Structure,Spectroscopy Reactivity

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