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Steroregular Aromatic Polyquinonimines and Related Polymers as Electrically Conductive, NLO-Active, Thermally Stable Polymers

机译:有机纳米芳香聚喹诺胺和相关聚合物作为导电,NLO活性,热稳定聚合物

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摘要

A new synthesis of high molecular weight polyaromatic quinonimines analogous to polyaniline was devised Aromatic diamines condensed with substituted p-benzoquinones or anthraquinone in presence of titanium tetrachloride/Dabco to yield a new family of soluble, orange, film forming polyaromatic quinonimines. Unlike polyaniline they were not electrically conductive. Polyaniline was alkylated by benzyl halides to form new soluble polyanilines. A cation radical mechanism was established for the oxidative polymerization of aniline. Fundamental information on the polymerization of imine monomers was obtained.

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