Synthesis and Characterization of the trans-IO2F5(2-) Dianion

机译：反式-O2O2F5（2-）二价阴离子的合成与表征

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The combination of CH3CN solutions of N(CH3)4F and a mixture of cis- and trans-N(CH3)4IO2F4 produces the novel trans-IO2F5(2-) anion. Under the given conditions, only the trans-IO2F4(-) anion acts as a fluoride ion acceptor, thus allowing the separation of isomerically pure, soluble cis-IO2F4(-) from insoluble trans-IO2F5(2-).

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作者
Boatz, J. A. ; Casteel, W. J. ; Christe, K. O. ; Dixon, D. A. ; Gerken, M.;
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年度 2003
页码 1-41
总页数 41
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Synthesis(Chemistry); Fluorides; Molecular orbitals; Cyanides; Electron acceptors; Iodine compounds;

机译：合成（化学）;氟化物;分子轨道;氰化物;电子受体;碘化合物;
入库时间 2022-08-29 11:03:49

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Synthesis and Characterization of the trans-IO2F5(2-) Dianion

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