Effect of Ligand Coordination on Complex Formation: Synthesis and Structural Studies of Metal(I) Salts Containing the N(SO2CF3)2 and OTeF5 Groups

摘要

The cisoid form is less common. In the CCDC, only 6 structures show this conformation where as the transiod form occurs in 15 remaining structures The cisoid conformation results from stronger cation-anion interaction The cisoid exclusively when anion is chelated to the metal center The transoid form dominates in structures containing a free anion NO structure known with both cisoid AND transoid geometry.