Spectroscopy of EDA Complexes at High Pressures. Iv. Absorption of Several Haloquinone Complexes in Polymer Matrices

摘要

Several haloquinone complexes were subjected to high pressures (0-20 kbar), and the resulting effects were registered in the charge transfer (CT) absorption spectra. The observed shift in the CT band maxima are discussed in terms of the various interaction terms, including CT forces, which contribute to the displacement of the ground relative to the excited CT state of the EDA-complex. The results indicate that the stronger complexes show the smaller red shiftor even a blue shift in this pressure range. CT intensities in the 1-20 kbar interval are observed to change by -15% to +40% in this group of related complexes. (Author)