Problems Relating to Amido-Derivatives of Metals and Metalloids. Volume I. Interaction of Amido-and Hydrido-Metal Compounds

摘要

The interaction of hydrido- and dimethylamido-metal compounds was studied. Three distinct types of reactions were found: (1) LMNMe2 + L'M'H to LM-M'L' + HNMe2; (2) Me3SnNMe2 + H-L'M'-C1 to L'M' + Me3SNC1.HNMe2; (3) Me3SnNMe2 + H-L'M'-C1 to Me3SnC1 + H-L'M'NMe2. A wide variety of compounds were synthesized using the above reactions. Emphasis was placed on metal to transition-metal bonded compounds, transition-metal hydrides, and amido derivatives of the Group IV B elements. Metal-metal bond structures were determined mass spectrometrically. The species L'M' that are produced by equation 2 demonstrated potentiality as catalysts. (Author)