Novel Chelated Biscarborane Transition Metal Complexes Formed Through Carbon-Metal sigma Bonds

摘要

A series of square planar and tetrahedral complexes have been prepared which contain the bidentate bis-carborane ligand sigma-bonded through carbon to a transition metal. These complexes of B1OC2H1O(-), dodecahydrodicarba-closo-borate (-1), exhibit unusual thermal and chemical stabilities. (Author)