Acid-Base Equilibria and Titrations and Electrochemical Equilibria in Acetonitrile

摘要

Very briefly discussed are studies which have been made of acid-base equilibria and titrations and also of conjugation in acetonitrile (AN) as a solvent. Dissociation constants of a host of uncharged and cationic acids have been determined, including acid-base indicators. The protonation constants of water, methanol, butanol and diethylether in AN have been determined. The heteroconjugation constants of sulfate and bisulfate ions in AN with uncharged hydrogen bond donors have been determined. (Author)