Studies of the Breakdown Mechanism of Polymers. VIII. The Thermal Decomposition of a Poly Tetraazolate,Triazole, Oxathiahydrazide, Thiadiazole,and Thiazole.

摘要

A poly(phenylene) imino tetraazolate, a poly N-phenyl-triazole, a polyoxathiahydrazide, a polythiadiazole,and a polydithiazole were subjected to decomposition in vacuum at temperatures up to 620C,and the decomposition mechanisms postulated on the basis of the mass spectroscopic data of the volatiles and the mass spectral,infrared,and elemental analysis of condensibles and residues. A summary of the proposed mechanisms is given. (Author)