Photoreactions of Tetrafluorodiphosphine with Nonsubstituted Olefins and Perfluoroolefins.

摘要

The photoreactions of P2F4 with C2H4, C3H6, 2-C4H8, C6H10, C2F4, and C3F6 have resulted in the formation of F2PCH2CH2PF2, CH3CHPF2CH2PF2, CH3CHPF2CHPF2CH3, C6H10(PF2)2, F2PCF2CF2PF2, and CF3CFPF2CF2PF2. No recoverable amount of comparable products was obtained in similar mixtures of P2F4 and 2-C4F8 or of P2F4 and C6F10. The new compounds were characterized by ir, nmr, and mass spectrometry. C6H10(PF2)2 displays temperature-dependent nmr spectra consistent with the trans isomer. (Author)