首页> 美国政府科技报告 >Reversible Addition of Carbon Monoxide to Tetracarbonyl bis(eta 5-pentamethylcyclopenta-dienyl)dimolybdenum.

【24h】

Reversible Addition of Carbon Monoxide to Tetracarbonyl bis(eta 5-pentamethylcyclopenta-dienyl)dimolybdenum.

机译：可逆地加成一氧化碳到四羰基双（η5-五甲基环戊二烯基）二钼。

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

The first example of the reversible addition of simple, two-electron donor ligands to a metal-metal triple bond is reported.

著录项

作者
Ginley, D. S.; Wrighton, M. S.;
展开▼
作者单位

展开▼
年度 1975
页码 1-4
总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Metalorganic compounds; Molybdenum compounds; Carbonyl compounds; Carbon monoxide; Addition reactions; Reaction kinetics; Chemical reactions; Reversible; Chemical bonds; Methyl radicals; Cyclopentenes; Dienes; Reprints; Dimolybdenum/Tetracarbonyl pentamethyl cyclopentadienes;

机译：金属有机化合物;钼化合物;羰基化合物;一氧化碳;加成反应;反应动力学;化学反应;可逆;化学键;甲基;环戊烯;二烯;重印;二钼/四羰基五甲基环戊二烯;

相似文献

外文文献
中文文献
专利

1. Reversible addition and elimination of alcohols by vicinal tetracarbonyl compound [J] . Maeda Shinya, Sudo Atsushi, Endo Takeshi Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第10期

机译：邻位四羰基化合物可逆地添加和消除醇
2. REGIO- AND STEREOSELECTIVE A(4)-UMPOLUNG REACTIONS OF ALPHA,BETA-UNSATURATED ESTERS TO 1,6-DICARBONYL COMPOUNDS BY ADDITION OF ENANTIOPURE NUCLEOPHILES TO RACEMIC TETRACARBONYL(ETA(3)-ALLYL)IRON(1+) COMPLEXES [J] . Enders D., Schmitz T., Lohray BB., Journal of Organometallic Chemistry . 1996,第1a2期

机译：通过对映体核糖基对苯二甲酰基（ETA（3）-烯丙基）铁（1+）络合物的加成反应，将不饱和酯类的α-，不饱和酯类的区域和立体选择性A（4）-UMPOLUNG反应生成1,6-二碳酰基化合物
3. Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)_4{C [J] . Al-Masri H.T., Mohamed B.M., Moussa Z., Helvetica chimica acta . 2013,第4期

机译：具有配体N，N-双（二苯基膦基）萘-1-胺（＝ N-（二苯基膦基）-N-萘-1-基-P，P-二苯基亚膦酰胺）的羰基6-金属衍生物的合成和表征。顺-四羰基[N-（二苯基膦基-κP）-N-萘-1-基-P，P-二苯基次膦酰胺-κP]钼的分子结构（顺式[[Mo（CO）_4 {C
4. Catalytic Addition of Amines to Carbon Monoxide by Rare Earth Metal Complexes : An Efficient Synthesis of N-Substituted Formamides [C] . Toshiaki Suzuki, Zhaomin Hou Symposium on Organometallic Chemistry . 2008

机译：通过稀土金属配合物催化添加胺至一氧化碳：高效合成N-取代的甲酰胺
5. Kinetics and mechanisms of the ligand substitution reactions of cyclopentadienyl M tetracarbonyl, indenyl M tetracarbonyl, M = niobium or tantalum, and molybdenum(2) (carbon monoxide)(6) [mu-eta(5),eta(5)-cyclopentadienylide-carbon alkyl(2)-cyclopentadienylide] with tributylphosphine, triphenylphosphine and triphenylphosphite. Photo-assisted carbonylation of supercritical ethane, ethane and methane in supercritical carbon dioxide by trans-chlorocarbonylbis(trimethylphosphine)rhodium(I). [D] . Lukmanova-Kline, Dinara Maratovna. 2001

机译：动力学和机制的环戊二烯基M四羰基，茚基M四羰基，M =铌或钽和钼（2）（一氧化碳）（6）[mu-eta（5），eta（5）-cyclopentadienylide-碳烷基（2）-环戊二烯基]与三丁基膦，三苯基膦和亚磷酸三苯酯。通过反氯羰基双（三甲基膦）铑（I）在超临界二氧化碳中对超临界乙烷，乙烷和甲烷进行光辅助羰基化。
6. Microwave Assisted Synthesis of Molybdenum and Tungsten Tetracarbonyl Complexes with a Pyrazolylpyridine Ligand. Crystal structure of cis-Mo(CO)4{ethyl3-(2-pyridyl)-1-pyrazolylacetate} [O] . Ana C. Coelho, Filipe A. Almeida Paz, Jacek Klinowski, 2006

机译：微波辅助合成吡唑基吡啶配体的钼和钨四羰基配合物。顺式-Mo（CO）4 {乙基3-（2-吡啶基）-1-吡唑基乙酸}}的晶体结构
7. Molybdenum/Bismuth Based Mixed Metal Oxide Catalysts for Selective Propylene Oxidation and Zeolite Membrane Protected Palladium/Alumina Catalysts for Selective Carbon Monoxide Oxidation and Application in a Process Loop Using a Propane Feed [O] . Maria Rivas Velazco, William McDonnell, Andrew W. J. Smith 2017

机译：基于钼/铋的混合金属氧化物催化剂，用于选择性丙烯氧化和沸石膜保护钯/氧化铝催化剂，用于使用丙烷进料在过程环中选择性一氧化碳氧化和应用

Reversible Addition of Carbon Monoxide to Tetracarbonyl bis(eta 5-pentamethylcyclopenta-dienyl)dimolybdenum.

摘要

著录项

相似文献

相关主题

期刊订阅