A Possible Mechanism for the Formation of Oxiranes in Reactions of Singlet Molecular Oxygen with Olefins.

摘要

MINDO/3 calculations indicate that peroxirane should react readily with Super 1 delta g O2 to form oxirane and ozone, and also with ethylene to form two molecules of peroxirane. The formation of oxiranes from olefines and super 1 delta g O2 is interpreted in this way and predictions are made concerning the effect of changes in the reaction conditions on the products of such reactions. (Author)