Vibrational Relaxation of DCl (nu=1) by Cl and Br Atoms and a HBr (nu=1) by Br Atoms.

摘要

The rates of vibrational relaxation of DCl (nu=1) by Cl and Br and measured as (5.5 + or - 1.6) times 10 to the -12 power and (2.3 + or - 0.7) times 10 to the -13 power cu-cm/molecule/sec, respectively. DCl is relaxed somewhat less rapidly than HCl in both cases. The rate for HBr (nu=1) relaxed by Br atoms is found to be (2.6 + or - 1.0) times 10 to the -12 power cc/molecule/sec.