首页> 美国政府科技报告 >Syntheses Involving Co-ordinatively Unsaturated Cyclopentadienyl-molybdenum and -tungsten Complexes. Molecular and Crystal Structure of (MoC(CF3)=C(CF3)C5H5(CF3C2CF3) (eta5-C5H5)).

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Syntheses Involving Co-ordinatively Unsaturated Cyclopentadienyl-molybdenum and -tungsten Complexes. Molecular and Crystal Structure of (MoC(CF3)=C(CF3)C5H5(CF3C2CF3) (eta5-C5H5)).

机译：涉及共同不饱和环戊二烯基 - 钼和钨配合物的合成。（moC（CF3）= C（CF3）C5H5（CF3C2CF3）（eta5-C5H5））的分子和晶体结构。

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Davidson, J. L.; Green, M.; Gordon, F.; Stone, A.; Welch, A. J.;
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年度 1976
页码 1-11
总页数 11
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Complex compounds; Synthesis(Chemistry); Organometallic compounds; Unsaturated hydrocarbons; Chemical bonds; Molybdenum compounds; Tungsten compounds; Pentadienes; Cyclic compounds; Reprints; Molybdenum/cyclopentadienyl; Tungsten/cyclopentadienyl;

机译：复合化合物;合成（化学）;有机金属化合物;不饱和烃;化学键;钼化合物;钨化合物;戊二烯;环状化合物;重印;钼/环戊二烯基;钨/环戊二烯基;

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专利

1. NOVEL HETEROCYCLES FROM ALKYLAMINO-BIS(TRIFLUOROMETHYL)BORANE, (CF3)(2)BNR(2), AND ISOCYANIDES - CRYSTAL AND MOLECULAR STRUCTURE OF (NC)(CF3)(2)B-CENTER-DOT-NHME(2), (CF3)(2)B-NME(2)-B(CF3)-NET=C-C(NME(2))=NET AND (CF3)(2)B-NME(2)-B(CF3)(2)-CH-C(=NME [J] . Ansorge A., Buchheimspiegel S., Burger H., Journal of Organometallic Chemistry . 1995,第1a2期

机译：（CF3）（2）BNR（2）和（-）（NC）（CF3）（2）B-CENTER-DOT-NHME（2）的晶体和分子结构的新型杂环（CF3）（2）B-NME（2）-B（CF3）-NET = CC（NME（2））= NET和（CF3）（2）B-NME（2）-B（CF3）（2） -CH-C（= NME
2. [2+3]CYCLOADDITION REACTIONS OF DIMETHYLAMINO-BIS(TRIFLUOROMETHYL) BORANE, (CF3)(2)BNME(2), WITH NITRILE OXIDES, NITRONES AND ME(2)C=SO2 - CRYSTAL AND MOLECULAR STRUCTURE OF (CF3)(2)B-NME(2)-(T)BUC=N-O AND (CF3)(2)B-NME(2)-CME(2)-S(=O)-O [J] . Brauer DJ., Pawelke G., Roth J., Journal of Organometallic Chemistry . 1996,第1期

机译：[2 + 3]二甲基氨基双（三氟甲基）硼烷，（CF3）（2）BNME（2）与腈的氧化物，氮和ME（2）的循环负载反应C（SO3）-（CF3）（ 2）B-NME（2）-（T）BUC =否AND（CF3）（2）B-NME（2）-CME（2）-S（= O）-O
3. Stabilization of the P(CF3)(2)(-) and P(C6F5)(2)(-) ions by coordination to pentacarbonyl tungsten: Structures of [18-crown-6-K]P(CF3)(2), [18-crown-6-K][W{P(CF3)(2)}(CO)(5)], and [18-crown-6-K][{W(CO)(5)}(2){mu-P(C6F5)(2)}]center dot THF [J] . Hoge B., Thosen C., Herrmann T., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第11期

机译：通过与五羰基钨配位来稳定P（CF3）（2）（-）和P（C6F5）（2）（-）离子：[18-crown-6-K] P（CF3）（2）的结构， [18-crown-6-K] [W {P（CF3）（2）}（CO）（5）]和[18-crown-6-K] [{W（CO）（5）}（2 ）{mu-P（C6F5）（2）}]中心点THF
4. I. THE SYNTHESES, SOLUTION BEHAVIOR, CRYSTAL STRUCTURES AND MAGNETIC PROPERTIES OF SOME IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES. II. THE CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A TRICOPPER(II) CLUSTER CONTAINING A TRIPLY BRIDGING CARBONATE GROUP. [D] . KOLKS, GARY ARNOLD. 1980

机译：I.某些咪唑基桥接铜（II）配合物的合成，溶液行为，晶体结构和磁性。二。含碳桥基的三铜（II）簇的晶体结构和磁性。
5. Synthesis and characterization of oxorhenium(V)–‘3+1’ mixed thiolate SNS/S and ONS/S complexes. Crystal and molecular structures of ReO(η3-SCH2C5H3NCH2S)(η1-C6H4Br-4-S) ReO(η3-SCH2C5H3NCH2O)(η1-C6H4X-4-S) (X=Cl OMe) ReO(η3-SCH2C5H3NCH2O)(η1-C6H4OCH3-4-CH2S) and ReO(η3-SCH2C5H3NCH2S)(η1-C5H4NH-2-S)Cl [O] . Xiaoyuan Chen, Frank J. Femia, John W. Babich, -1

机译：氧化or（V）– 3 + 1混合硫醇盐SNS / S和ONS / S配合物的合成与表征。 ReO（η3-SCH2C5H3NCH2S）（η1-C6H4Br-4-S）ReO（η3-SCH2C5H3NCH2O）（η1-C6H4X-4-S）（X = ClOMe）ReO （η3-SCH2C5H3NCH2O）（η1-C6H4OCH3-4-CH2S）和ReO（η3-SCH2C5H3NCH2S）（η1-C5H4NH-2-S） Cl
6. The preparation of thiazyltrifluoromethane, CF3SN, the hexachloro-3-cyclopentenylidenaminosulfides C5Cl6NSX (X = CF3, Cl, NSO, SCF3, C5Cl6N) and the crystal structures of C5Cl6NSX (X = CF3, Cl) [O] . Alois Haas L, Thomas Mischo 1989

机译：噻唑氟甲烷，CF3SN，六氯-3-环戊烯基氨基磺酰硫化物C5Cl6NSx（X = CF3，Cl，NSO，SCF3，C5CL6N）和C5Cl6NSX（X = CF3，CL）的晶体结构的制备
7. Formation of Sixteen-Electron Alkyne Complexes by Reaction of Halogeno(Tricarbonyl) (eta5-Cyclopentadienyl)-Molybdenum and -Tungsten Complexes with Alkynes; Crystal and Molecular Structure of (WCl (CF3C2CF3) sub 2-(eta5-C5H5)). [R] . Davidson, J. L., Green, M., Gordon, F., 1975

机译：通过卤素（三羰基）（η5-环戊二烯基） - 钼和钨配合物与炔烃的反应形成16-电子炔烃配合物; （WCl（CF3C2CF3）sub 2-（eta5-C5H5））的晶体和分子结构。

Syntheses Involving Co-ordinatively Unsaturated Cyclopentadienyl-molybdenum and -tungsten Complexes. Molecular and Crystal Structure of (MoC(CF3)=C(CF3)C5H5(CF3C2CF3) (eta5-C5H5)).

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