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Formation of ETA3-Bonded Lactone Complexes and Eight-Membered Ring Metallacycles with Ketene Groups by the Insertion of Acetylenes into Carbon-Molybdenum and -Tungsten Alpha Bonds.

机译：通过将乙炔插入碳 - 钼和钨α键中形成具有烯酮基团的ETa3-键合的内酯络合物和八元环金属环。

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作者
Green, M.; Nyathi, J. Z.; Scott, C.; Gordon, F.; Stone, A.;
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年度 1977
页码 1-17
总页数 17
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Lactones; Ketenes; Metal complexes; Synthesis(Chemistry); Cyclic compounds; Acetylene; Molybdenum compounds; Tungsten compounds; Chemical bonds; Reprints;

机译：内酯; Ketenes;金属配合物;合成（化学）;环状化合物;乙炔;钼化合物;钨化合物;化学键;重印;

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机译：钯辅助的区域选择性烯烃插入并消除了氢-钼和-钨键的β-氢。钯和铂与钼和钨的异双核氢化物的合成及反应
2. A comprehensive study of [2 + 2] cycloadditions and ene reactions of alkynyl chromium and tungsten carbene complexes with enol ethers and ketene acetals and of the stereochemistry of the electrocyclic ring opening of cyclobutenyl carbene complexes [J] . William D. Wulff, Katherine L. Faron, Jing Su, Journal of the Chemical Society, Perkin Transactions 1 . 1999,第2期

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3. Convenient preparation of ytterbium(III) chalcogenolate complexes by insertion of ytterbium into chalcogen-chalcogen bonds. Application in the ring-opening of epoxides [J] . Dowsland Jennifer, McKerlie Fiona, Procter David J. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第25期

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4. NOVEL LIGAND TRANSFORMATIONS WITHIN COMPLEXES OF TUNGSTENOCENE (MIGRATORY INSERTION, METALLOCYCLOIMIDE, BRIDGING-OXO, TERMINAL-OXO, HETEROALLENE ACTIVATION). [D] . JERNAKOFF, PETER. 1986

机译：钨茂金属内的新配体转化（迁移插入，金属环酰亚胺，桥联-氧代，末端-氧代，杂芳烃活化）。
5. Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes. Applications to Total Syntheses of Epilachnene Yuzu Lactone Ambrettolide Epothilone C and Nakadomarin A [O] . Chenbo Wang, Miao Yu, Andrew F. Kyle, -1

机译：通过大环二取代烯烃Ž的高效和选择性形成闭环由钼或钨为基础的monoaryloxide吡咯（map）配合物催化复分解反应（RCm）反应。应用Epilachnene的全合成柚子内酯黄葵内酯埃博霉素C和那卡多莫林一
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机译：钯辅助区域烯烃插入和B-氢消除氢 - 钼和-Tungsten键。钯和钨钯和铂钯和铂的合成与反应

Formation of ETA3-Bonded Lactone Complexes and Eight-Membered Ring Metallacycles with Ketene Groups by the Insertion of Acetylenes into Carbon-Molybdenum and -Tungsten Alpha Bonds.

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