The Preparation of (3-3-(Ph3P)2-3-H-4-(polystyrylmethyl)-3-1-2-Rhoda Carborane); A Polymer-Bound Metallocarborane Catalyst.

摘要

The compound (3-3-(Ph3P)2-3-H-4-(polystyrylmethyl)-3-1-2-RhC2B9H10)(I) was synthesized from ((Ph3P)3RhC1) and (9-(polystyrylmethyl)-7-8-C2B9H11) M+ (II; M = Na or K). Characterization of (I) includes infrared, visible, and X-ray photoelectron spectroscopy and elemental analysis. The polymer-bound carborane (II) was isolated from the reaction of (7,8-C2B9H11)2- with Merrifield's Peptide resin.