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Octa(isopropoxy)Dimolybdenum and Bis(nitrosyl)Hexa(Isopropoxy)dimolybdenum. Structure and Bonding in Compounds Containing Molybdenum Atoms with Fourteen Valence Shell Electronic Configurations.

机译：Octa（异丙氧基）Dimolybdenum和Bis（亚硝酰基）Hexa（异丙氧基）二钼。含有十四价壳电子构型的含钼原子的化合物的结构和键合。

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The compounds Mo2(OPr(i))6(NO)2, I, and Mo2(OPr(i)8, II have been structurally characterized. Each compound has rigorous inversion symmetry and virtual C2v symmetry and in each there is essentially trigonal bipyramidal coordination about each molybdenum atom.

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Chisholm, M. H.; Cotton, F. A.; Extine, M. W.; Kelly, R. L.; Reichert, W. W.;
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年度 1977
页码 1-14
总页数 14
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Metalorganic compounds; Chemical structure; Chemical bonds; Molybdenum compounds; Nitroso compounds; Propyl radicals; Oxygen compounds; Valence bands; Electronic states; Metal metal bonds; Alkoxy radicals; Inversion; Symmetry; Planar structures; Ligands; Molybdenum/octa(isopropoxy)-di); Molybdenum/bis(nitrosyl)-hexa(isopropoxy)-di);

机译：金属有机化合物;化学结构;化学键;钼化合物;亚硝基化合物;丙基;氧化合物;价带;电子态;金属金属键;烷氧基;反转;对称性;平面结构;配体;钼/八（异丙氧基） - 二）;钼/二（亚硝酰基） - 六（异丙氧基） - 二）;
入库时间 2022-08-29 11:37:21

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机译：钨 - 钨三重键。 8.（1）钨的双核醇盐（III）和六 - （异丙氧基）二吡啶并二嗪的结构表征。具有四配位钨原子的第一种化合物由三键结合。

Octa(isopropoxy)Dimolybdenum and Bis(nitrosyl)Hexa(Isopropoxy)dimolybdenum. Structure and Bonding in Compounds Containing Molybdenum Atoms with Fourteen Valence Shell Electronic Configurations.

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