Reactions of Metal-to-Metal Multiple Bonds. 3. Addition of Nitric Oxide to Hexakis(alkoxy)-dimolybdenum Compounds. Preparation and Properties of Bis(nitrosyl)hexakis(alkoxy)dimolybdenum Compounds and Structural Characterization of the Isoproproxy Derivative.

摘要

The occurrence of compounds containing metal-to-metal multiple bonds is now a well documented facet of transition metal chemistry. In this series we are studying the reactions of such compounds with regard to their ability (1) to undergo reactions of the type well documented in mononuclear chemistry and (2) to act as building blocks for the systematic synthesis of new cluster (polynuclear) compounds. Both have important catalytic implications.