The Jahn-Teller Effect in the Lowest Charge Transfer State of UF6.

机译：UF6最低电荷转移状态下的Jahn-Teller效应。

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摘要

The neat and mixed crystal emission spectra of UF6 are analyzed. The data are interpreted as being indicative of a substantial molecular Jahn-Teller interaction in the excited charge transfer state. Using a modified Franck-Condon analysis for a 3-dimensional vibrational space, it is found that D(5) is approx. 2.02 and that the excited state is distorted along each of three v5 coordinates by roughly 0.09 A.

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Bernstein, E. R.; Meredith, G. R.; Webb, J. D.;
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年度 1978
页码 1-33
总页数 33
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Charge transfer; Uranium compounds; Fluorides; Excitation; Emission; Crystals; Uranium hexafluoride; John-Teller effect; Franck-Condon principle; Harmonic oscillators;

机译：电荷转移;铀化合物;氟化物;激发;发射;晶体;六氟化铀; John-Teller效应; Franck-Condon原理;谐波振荡器;

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1. Jahn-Teller and coupled Jahn-Teller/Renner-Teller effects in the calculation of adiabatic-to-diabatic transformation angle for the lowest three (2)A ' states of NH2 (NHH) [J] . Srivastava S., Baer M., Sathyamurthy N. Molecular physics . 2015,第5a6期

机译：Jahn-Teller和耦合的Jahn-Teller / Renner-Teller效应在NH2（NHH）的最低三（2）A'状态的绝热至绝热转变角的计算中
2. The lowest-energy charge-transfer state and its role in charge separation in organic photovoltaics [J] . Nan Guangjun, Zhang Xu, Lu Gang Physical chemistry chemical physics: PCCP . 2016,第26期

机译：最低能量的电荷转移状态及其在有机光伏中电荷分离中的作用
3. The lowest-energy charge-transfer state and its role in charge separation in organic photovoltaics [J] . Nan Guangjun, Zhang Xu, Lu Gang Physical chemistry chemical physics: PCCP . 2016,第26期

机译：最低能量的电荷转移状态及其在有机光伏中电荷分离中的作用
4. The crucial role of Jahn-Teller effect in the formation of orbital and magnetic structures of charge ordered manganite R{sub}0.5A{sub}0.5MnO{sub}3 [C] . L. E. Gontchar, A. E. Nikiforov, S. E. Popov NATO Advanced Research Workshop on Colossal Magnetoresistance and Vibronic Interactions, and the Fifteenth International Symposium on the Jahn-Teller Effect . 2001

机译：Jahn-Teller效应在轨道和磁结构形成中的关键作用有序锰岩R {Sub} 0.5A {} 0.5Mno {sub} 3
5. (1) Flipped-out and switched-on ionophores. (2) Conformationally controlled intramolecular charge transfer complexes. (3) Intramolecular charge transfer ionophores [D] . Durocher, David Thomas. 1990

机译：（1）翻转并打开离子载体。（2）构象控制的分子内电荷转移复合物。（3）分子内电荷转移离子载体
6. The Origin of the Low-Energy Form of Photosystem I Light-Harvesting Complex Lhca4: Mixing of the Lowest Exciton with a Charge-Transfer State [O] . Elisabet Romero, Milena Mozzo, Ivo H.M. van Stokkum, 2009

机译：光系统I低能量形式的光收集复合体Lhca4的起源：最低激子与电荷转移态的混合
7. Lowest energy electronic transition in aqueous Cl ^- Salts: Cl ^- → (H 2O) 6 charge transfer transition [O] . Xiong, K, Asher, SA 2011

机译：Cl ^{-水溶液中最低能量的电子跃迁：Cl ^{-→（H 2 O） 6 电荷转移跃迁}}

The Jahn-Teller Effect in the Lowest Charge Transfer State of UF6.

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