Novel Organophosphorus and Organonitrogen Derivatives and Their Use for the Synthesis of Unusual Transition Metal Complexes

摘要

New research results in synthetic organophosphorus and coordination chemistry are summarized with particular emphasis on the following: (1) Complexes of the alkylaminobis (difluorophosphines) RN(PF2)2 exhibiting novel structural features prepared by reactions of the ligands with carbonyls of chromium, molybdenum, tungsten, iron, cobalt and nickel and cyclopentadienylmetal carbonyls of vanadium, molybdenum, tungsten, manganese, and iron; and (2) Polyphosphines containing terminal dialkylamino and methoxy groups with preliminary results on metal complexes of the latter. (Author)