The Precursor of an Extraordinarily Reactive Homogeneous Hydrogenation Catalyst. Synthesis, Structure and Reactions of (closo-1,3-micron-(n2-3,4-buten-1-y1)-3-H-3-PPh3-3,1,2,-RhC2B9H10)

摘要

The synthesis, reactions and structure of the catalyst precursor (closo-1,3-Mu-(eta(2)-3,4-buten-lyl)-3-H-3-PPh3-3,1,2,-RhC2B9H10) (i) and the initial rates of some alkene hydrogenations catalyzed by (I) are reported. (Author)