New Type of Metallo-Organic Polymer: Bimetalloporphyrins. Investigating a New Chemistry of Metallophthalocyanines

摘要

The creations (synthesis) of out of plane and skewered metalloporphyrins were reported. The structure of bis(phthalocyaninato)neodymium(III) was elucidated by the x-ray diffraction analysis. From the conductivity of (Pc2Nd)(-)H(+), a new hydrogen bonded polymer structure in crystal solid state without solvent was proposed. (Author)