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Homogeneous Activation of the C-H Bond. Formation of Phenylsiloxanes from Benzene and Silicon Hydrides

机译：C-H键的均相活化。由苯和硅氢化物形成苯基硅氧烷

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Gustavson, W. A.; Epstein, P. S.; Curtis, M. D.;
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年度 1982
页码 p.1-7
总页数 7
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Reaction kinetics; Siloxanes; Phenyl radicals; Benzene; Hydrides; Silicon compounds; Reprints;

机译：反应动力学;硅氧烷;苯基;苯;氢化物;硅化合物;重印;

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1. C-H Bond Activation during and after the Reactions of a Metallacyclic Amide with Silanes: Formation of a m-Alkylidene Hydride Complex, Its H-D Exchange, and b-H Abstraction by a Hydride Ligand [J] . Li Wang, Seth C. Hunter, Zhimin Song, Chemistry: A European journal . 2014,第20期

机译：金属环酰胺与硅烷反应期间和之后的C-H键活化：间亚炔氢化物配合物的形成，其H-D交换和由氢化物配体的b-H提取
2. C-H bond activation reactions in π-allene-osmium-triisopropylphosphine complexes with cyclopentadienyl or hydridotris(pyrazolyl)borate ligands: Formation of isopropenyldiisopropylphosphine versus hydride-alkenylcarbyne derivatives [J] . Castro-Rodrigo R., Esteruelas M.A., López A.M., Organometallics . 2010,第18期

机译：具有环戊二烯基或氢化三（吡唑基）硼酸酯配体的π-丙二烯-os-三异丙基膦配合物中的C-H键活化反应：异丙烯基二异丙基膦与氢化物-烯基碳炔衍生物的形成
3. C-H bond activation of terminal allenes: Formation of hydride- alkenylcarbyne-osmium and disubstituted vinylidene-ruthenium derivatives [J] . Collado A., Esteruelas M.A., López F., Organometallics . 2010,第21期

机译：末端异戊烯的C-H键活化：氢化物-烯基碳炔-和二取代的亚乙烯基-钌衍生物的形成
4. INTERMOLECULAR C-H BOND ACTIVATION OF BENZENE BY A VANADIUM(III) ALKYLIDENE INCLUDING THE STEPWISE CONVERSION TOBENZYNE [C] . Jose G. Andino, Uriah J. Kilgore, Maren Pink American Chemical Society National Meeting . 2010

机译：钒（III）烷基化苯的分子间C-H键活化，包括逐步转化为细胞
5. Part one. Catalytic activation of organosilicon and organohalide compounds with dinuclear nickel hydride Part two. Mechanistic study and kinetic modeling of single-site catalytic olefin polymerization with zirconium salan. [D] . Smith, Erin Elizabeth. 2012

机译：第一部分。用双核氢化镍催化活化有机硅和有机卤化物。第二部分。锆锆单点催化烯烃聚合的机理研究和动力学模型。
6. C-H Bond Functionalization via Hydride Transfer: Formation of α-Arylated Piperidines and 1234-Tetrahydroisoquinolines via Stereoselective Intramolecular Amination of Benzylic C-H Bonds [O] . Paul A. Vadola, Ignacio Carrera, Dalibor Sames -1

机译：通过氢化物转移C-H键官能：通过苄型C-H键的立体选择性分子内胺化α芳基化哌啶和1234-四氢异喹啉的形成
7. C-H bond activation of terminal allenes: Formation of hydride- alkenylcarbyne-osmium and disubstituted vinylidene-ruthenium derivatives [O] . Collado Alba, Esteruelas Miguel A., López Fernando, 2012

机译：末端异戊烯的C-H键活化：氢化物-烯基碳炔-和二取代的亚乙烯基-钌衍生物的形成
8. Homogeneous Activation of the C-H Bond. Formation of Phenylsiloxanes from Benzene and Silicon Hydrides. [R] . Gustavson, W. A., Epstein, P. S., Curtis, M. D. 1982

机译：C-H键的均相活化。由苯和硅氢化物形成苯基硅氧烷。

Homogeneous Activation of the C-H Bond. Formation of Phenylsiloxanes from Benzene and Silicon Hydrides

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