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Investigation of Denitration Reactions of Unsymmetrical Trinitrotoluenes to 2,4-Dinitrotoluene

机译：不对称三硝基甲苯与2,4-二硝基甲苯脱硝反应的研究

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摘要

Several methods were tested for reductive denitration of 2,4,5-trinitrotoluene to 2,4-dinitrotoluene. Tin-hydrochloric acid and ion-hydrochloric acid gave a 10% yield of the desired material; other reagents gave none.

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作者
Okamoto, Y.; Attarwala, S. T.; Bochnik, M.;
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年度 1982
页码 p.1-25
总页数 25
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
TNT; Nitration; Munitions industry; Chemical reactions; Calcium hydrides; Potassium compounds; Formates; Hydrochloric acid;

机译：TNT;硝化;弹药工业;化学反应;氢化钙;钾化合物;甲酸盐;盐酸;

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专利

1. Comprehensive Investigations of Kinetics of Alkaline Hydrolysis of TNT (2,4,6-Trinitrotoluene), DNT (2,4-Dinitrotoluene), and DNAN (2,4-Dinitroanisole) [J] . Liudmyla Sviatenko, Chad Kinney, Leonid Gorb, Environmental Science & Technology . 2014,第17期

机译：TNT（2,4,6-三硝基甲苯），DNT（2,4-二硝基甲苯）和DNAN（2,4-二硝基苯甲醚）碱性水解动力学的综合研究
2. Effects of chronic 2,4,6,-trinitrotoluene, 2,4-dinitrotoluene, and 2,6-dinitrotoluene exposure on developing bullfrog (Rana catesbeiana) tadpoles [J] . Norka E. Paden, Ernest E. Smith, Jonathan D. Maul, Ecotoxicology and Environmental Safety . 2011,第4期

机译：慢性2,4,6，-三硝基甲苯，2,4-二硝基甲苯和2,6-二硝基甲苯暴露对发育中的牛蛙（Rana catesbeiana）t的影响
3. Acute toxicity of 2,4,6-trinitrotoluene, 2,4-dinitrotoluene, and 2,6-dinitrotoluene in the adult bullfrog (Lithobates catesbeiana). [J] . Paden NE, Smith EE, Kendall RJ Bulletin of Environmental Contamination and Toxicology . 2008,第6期

机译：成年牛蛙（Lithobates catesbeiana）中2,4,6-三硝基甲苯，2,4-二硝基甲苯和2,6-二硝基甲苯的急性毒性。
4. Ab initio calculation of Raman vibrational signatures of 2,4-dinitrotoluene, 2,6-dinitrotoluene and 2,4,6-trinitrotoluene [C] . Jairo Castillo-Chara, Cesar Manrique-Bastidas, Nairmen Mina, Chemical and Biological Sensors for Industrial and Environmental Monitoring III; Proceedings of SPIE-The International Society for Optical Engineering; vol.6756 . 2007

机译：从头算计算2,4-二硝基甲苯，2,6-二硝基甲苯和2,4,6-三硝基甲苯的拉曼振动特征
5. Removal of 2,4-dinitrophenol and 2,4-dinitrotoluene from water using surfactant-modified activated carbon. [D] . Cota-Espericueta, Alma Delia. 2003

机译：使用表面活性剂改性的活性炭从水中去除2,4-二硝基苯酚和2,4-二硝基甲苯。
6. Aerobic Growth of Escherichia coli with 246-Trinitrotoluene (TNT) as the Sole Nitrogen Source and Evidence of TNT Denitration by Whole Cells and Cell-Free Extracts [O] . Ben Stenuit, Laurent Eyers, Raoul Rozenberg, 2006

机译：以246-三硝基甲苯（TNT）为唯一氮源的大肠杆菌的有氧生长以及全细胞和无细胞提取物对TNT脱硝的证据
7. Nitroaromatic explosives (Nitrobenzene; 2-Nitrotoluene; 3-Nitrotoluene; 4-Nitrotoluene; 1,2-Dinitrobenzene; 1,3-Dinitrobenzene; 2,4-Dinitrotoluene; 2,6-Dinitrotoluene; 2,4,6-Trinitrotoluene) in urine Biomonitoring Methods, 2015 [O] . M. Bader, R. Heinrich-Ramm, U. Knecht, 2016

机译：硝基芳族炸药（硝基苯; 2-硝基甲苯; 3-硝基甲苯; 4-硝基甲苯; 1,2-二硝基苯; 1,3-二硝基苯; 2,4-二硝基甲苯; 2,4,6-三硝基甲苯）尿液生物监测方法，2015
8. Investigation of Denitration Reactions of Unsymmetrical Trinitrotoluenes to 2,4-Dinitrotoluene. [R] . Okamoto, Y., Attarwala, S. T., Bochnik, M. 1982

机译：不对称三硝基甲苯与2,4-二硝基甲苯脱硝反应的研究。

Investigation of Denitration Reactions of Unsymmetrical Trinitrotoluenes to 2,4-Dinitrotoluene

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