Hydrolysis of Dibromo fluoromethyl triphenylpho sphonium Bromide

机译：二溴氟甲基三苯基溴化鏻的水解

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Hydrolysis of (Ph3PCFBr2)Br(-) afforded a high yield of dibromofluoromethane and triphenylphosphine oxide. Hydrolysis in the presence of a radioactive isotope of bromine gave evidence that the mechanism of this reaction proceeds via the dibromofluoromethide ion and not via a bromofluorocarbene intermediate. (Author)

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作者
Burton, D. J.; Flynn, R. M.; Manning, R. G.; Kessler, R. M.;
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年度 1982
页码 p.1-7
总页数 7
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Hydrolysis; Bromides; Phosphonium compounds; Fluorine compounds; Methyl radicals; Phenyl radicals; Oxides; Methane; Salts; Reprints;

机译：水解;溴化物;鏻化合物;氟化合物;甲基;苯基;氧化物;甲烷;盐;重印;

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机译：溴化汞（II）与三苯基膦和杂环硫酮的合成，表征和研究。 [双（三苯膦）二溴汞（II）]和[二溴（嘧啶-2-硫代）（三苯膦）的晶体结构
2. Kinetic and Mechanistic Study on the Thermal Reactivity of Stabilized Phosphorus Ylides,Part 3:[(Acetyl)(arylcarbamoyl)-methylene] triphenylphos-phoranes and [(Alkoxy-carbonyl)(arylcarbamoyl)-methylene]triphenylphos-phoranes and Their Thiocarbamoyl A [J] . R.ALAN AITKEN, NOURIA A.AL-AWADI, GRAHAM DAWSON International Journal of Chemical Kinetics . 2007,第26期

机译：稳定的磷鎓叶立德的热反应动力学和机理研究，第3部分：[（乙酰基）（芳基氨基甲酰基）-亚甲基]三苯基膦-和-[（烷氧基-羰基）（芳基氨基甲酰基）-亚甲基]三苯基膦-硫代氨基甲酸
3. Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide [J] . An Lun, Xiao Yu-Lan, Min Qiao-Qiao, Angewandte Chemie . 2015,第31期

机译：芳基硼酸和氟代甲基溴之间的镍催化交叉偶合，易于获得氟代甲基化的芳烃
4. SELECTIVE BROMINATION OF METHANE OVER SOLID ACID CATALYSTS AND POLY (4-VINYL PYRIDINE) CATALYZED HYDROLYSIS AND METHANOLYSIS OF METHYL BROMIDE [C] . G. K. Surya Prakash, Patrice Batamack, Juan C. Colmenares, AIChE spring meeting;Global congress on process safety . 2011

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6. 4,5-Dibromo-1,2-dimethyl-1H-imidazol-3-ium bromide [O] . Mebarek Bahnous, Abdelmalek Bouraiou, Sofiane Bouacida, 2015

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8. Catalytic Hydrolysis of p-Nitrophenyldiphenyl Phosphate in a CTAB (Cetyltrimethylammonium Bromide) Microemulsion [R] . Mackay, R. A., Durst, H. D., Longo, F. R., 1989

机译：CTaB（十六烷基三甲基溴化铵）微乳液催化水解对硝基苯基二苯基磷酸酯

Hydrolysis of Dibromo fluoromethyl triphenylpho sphonium Bromide

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