Synthetic Studies of Antimony Sulfur Iodide and Predictions/Synthesis of New Nitrogen Containing Crystal Structures

摘要

SbSI been grown to needles approximately 1 mm long by hydrothermal techniques. the curious bonding in this compound is discussed. The possible use of Pauling's Second Crystal Rule for predicting anion aliovalent substitution in crystallographic isotopes, particularly of nitrogen, is examined. Bond length/bond strength sums are also reviewed for structures where N-substitution is known. It is predicted that many nitrogen-phosphate mineral type structures can be made. (Author)