Compound Class Quantitation of JP-5 Jet Fuels by High Performance Liquid Chromatography/Differential Refractive Index Detection

摘要

Fuel composition effects are known to significantly affect jet turbine engine performance. Currently, one important composition parameter, total aromatics (% v/v), is actually defined in all JP-4 and JP-5 military fuel specifications governing procurement. This report outlines an improved method for defining not only total aromatics but also the two sub-classes, mono-cyclic and di-cyclic aromatics, that make up the total aromatics in JP-5. Special emphasis has been placed on the accurate and precise quantitation of saturates, mono-cyclic and di-cyclic aromatic fractions. This has been accomplished for fuels in the JP-5 distillation range by direct quantitation with a low sensitivity differential refractive index (DRI) detector. The detector is first calibrated by an appropriate standard and the response factors (= weight/area) for each compound class are used by a calculating electronic integrator/recorder to report directly each subsequently analyzed fuel in weight percent for each compound class. The analysis of each fuel is fast and very precise. Accuracy appears to be quite good and is under further investigation. Long term analytical stability has proven (up to one year). Quantitative data for thirteen JP-5 fuels have been compared with data from fluorescence indicator absorption, HPLC/GC (High Performance Liquid Chromatography/Gas Chromatography) and gravimetric data. The thirteen fuels include several experimental jet fuel blends and one shale JP-5 fuel.