Micron-Spaced Platinum Interdigitated Array Electrode: Fabrication, Theory and Initial Use

摘要

An interdigitated array (IDA) electrode composed of 40 pairs of 0.3 micrometers thick Pt fingers 3.5 micrometers wide and separated by 2.5 micrometer gaps of insulating borosilicate glass substrate has been fashioned by a modified microlithographic technique. The two IDA is applied to measurement of redox electron conduction through films of poly-Os(bpy)2 (vpy)2 (C1O4)2, poly-CRu(bpy)2 (vpy)2 (C104)2, and Prussian Blue that had been electrochemically deposited over the Pt fingers and in te insulating gaps. Appropriate theory for using the IDA for this purpose is developed. Electrochemically generated luminescence from solutions of Ru(bpy)3 (2+) is also observed with the IDA. (Author)