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7-Phosphanorbornene Derivatives as Precursors and Amides of Two-co-ordinate Thiophosphenous O-Acid

机译:7-磷杂蒽醌衍生物作为前体和双配位硫代磷酸O-酸的酰胺

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摘要

Heating thiophosphinate O-esters and thiophosphinamides having the 7-phosphanorbornene framework results in elimination of fragments that are derivatives of thiophophenous O-acid; they are trapped by cycloaddition with 2,3-dimethylbutadiene to form 2,5-dihydrophospholes.

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