Synthesis of New Stereoregular Fluoropolymers

摘要

Four papers are summarized the first presents an overview and survey of the work carried out. In the initial stages of the work a broadly based survey of metathesis polymerization of fluorinated monomers was conducted; more detailed studies of particular monomer types were conducted. All the monomers investigated are reviewed along with other systems examined in related projects. A detailed study of the polymerization of 2,3-bis(trifluoromethyl) bicyclo(2.2.1)hepta-2.5-diene, again relevant results from related projects are included was discussed in the second paper. The third paper concerns a detailed study of the polymerization of 5-trifluoromethylbicyclo(2.2.1)hept-2-ene, and is exclusively the work of this project. The fourth paper concerns 2-trifluoromethylbicyclo(2.2.1)hepta-2,5-diene as monomer.