Preparation of Titanium Nitride and Titanium Carbonitride by the Preceramic Polymer Route

摘要

The pyrolysis of selected titanium amides in a stream of ammonia gives titanium nitride. In a stream of argon titanium carbonitride is produced. We have developed useful routes for the preparation of silicon and boron carbonitrides and nitrides by the pyrolysis of suitable polymeric precursors, and we were interested in developing such an approach for the synthesis of titanium carbonitride and nitride.